Goats milk should be a fine milk resource for your young calves. To help prevent pneumonia make sure the facility being used is well ventilated, the calves are dry and well bedded, and nose to nose contacted is avoided. The high temperatures indicate infectious disease. A Florida presentation last month was similar to your symptoms and he was discussing mycoplasma. You need to get an opinion from a veterinarian.
Mike Hutjens, Extension Dairy Specialist, U of IL - Illini DairyNET
Neil Broadwater, Regional Extension Educator-Dairy - U of MN